Invited: Scalable Production of Nanowire Arrays and Powders Using Plasmas
Scalable production method for nanowires of low-melting metal oxides: A novel atmospheric microwave plasma reactor is designed to process about a kilogram of nanowires per day and has already been demonstrated for the synthesis of tin oxide, zinc oxide and aluminum oxide nanowires.1 The resulting nanowires are 50-100 nm in diameter and several microns long.
Scalable production of titania and related metal oxide nanowires: We report a new ultrafast (reaction time on the scale of a minute) gas-phase method for synthesizing highly crystalline TiO2 nanowires (NWs) using direct oxidation of either Ti metal (foils or powders) or spherical TiO2 powders using an atmospheric pressure microwave plasma reactor.2 The current state of the art methods involve long reaction time scales (~1 day) for synthesis of TiO2 NWs.
Low-temperature synthesis of nanowire arrays of silicon and related materials: This presentation will also highlight our recent experiments on the synthesis of silicon nanowire arrays at temperatures lower than 300 C.
This presentation will also highlight our efforts in utilizing the nanowire based materials toward various energy conversion and storage applications including dye sensitized solar cells, lithium ion batteries, and photoelectrochemical water splitting.
- V. Kumar, J-H. Kim, C. Pendyala, B. Chernomordik, and M.K. Sunkara, “Gas-Phase, Bulk Production of Metal Oxide Nanowires and Nanoparticles Using a Microwave Plasma Jet Reactor”, J. Phys. Chem. C., 112, 46, 17750-17754 (2008).
- V. Kumar, J-H. Kim, J.B. Jasinski, E.L. Clark, and M.K. Sunkara, “Alkali assisted, atmospheric plasma production titania nanowire powders and arrays”, Crystal Growth and Design, 11 (7), 2913 (2011).