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Conformal Electrodeposition for All-Solid-State 3D Thin-Film Batteries
Solid materials with intrinsically high ion conductivity (~10-3 S.cm) do exist, but are not electrochemically stable. Vice versa, electronically insulating electrolytes with a large electrochemical window and good chemical stability to metallic Li are known, but typically have intrinsically low ionic conductivities (<10-6 S cm). By scaling down the electrolyte thickness, an overall acceptable ionic conductivity can be obtained even for material with poor ionic conductivity. The latter assumes conformal and pinhole-free coverage over large effective surface areas with large aspect ratio features. ALD is a surface sensitive technique that can provide superior conformal coatings of high-aspect ratio features, crevices and corners and is suitable for (but not limited to) ultra-thin films. In this paper, the requirements for functional and viable thin-film stacks will be discussed. The need for conformal deposition techniques such as ECD, ALD and MLD for electrode, electrolyte and buffer layers will be addressed.
The mechanical integrity of the all-solid state stack in corners and confined spaces is a tangible issue. Considerable mechanical stress may build up during charge and discharge due to the rigid nature of the inorganic crystals and glasses that make up the battery stack. Furthermore, in-diffusion of at interfaces may consume part of the electrode which next to capacity and power loss can affect device reliability. In this paper, the importance of thin buffer layers will be discoursed.
Part of the current collector/anode/electrolyte/cathode/current collector can be made by electrochemical deposition. Electronically resistive materials such as oxides and dielectric polymers can be electrodeposited with extreme conformality as a result of the self-limiting kinetics. In this paper we will show the electrodeposition of MnO2 as potential positive Li-ion electrode and the electro-polymerization of poly phenylene oxide (PPO) as two examples were ECD can built part the battery stack on micro-structured surfaces with great potential for cost-effective up scaling to large area foil-based processing.