About Microwave Solvothermal Synthesis of Solid Solutions LiFexMn1-xPO4/C and Their Electrochemical Properties
It is believed that the formation of solid solutions (3) between LiFePO4 and LiMnPO4 (LiFexMn1-xPO4) remarkably improves the electronic conductivity. This strategy seems auspicious, since the higher potential of LiMnPO4 (4.1V vs. Li/Li+) compared to LiFePO4 (3.5V vs. Li/Li+) leads to a superior energy density of the resulting lithium-ion battery.
Therefore, we report a microwave solvothermal synthesis of phospho-olivines LiMPO4(M= Fe, Mn, Co, Ni) and mixtures thereof within 10 minutes of reaction time. It is common for increasing the electronic conductivity of phospho-olivines to use one of the following problem-solving approaches: Coating with a conducting phase (4), minimizing of the particles in size (5) and doping with positive divalent\trivalent metal ions and\or fluorine (6).
Morphology of the samples is analyzed by scanning electron microscopy (SEM) as shown in figure 1. Additionally all powders are analyzed by X-ray powder diffraction (XRD), energy dispersive X-ray analysis (EDX), cyclic voltammetry (CV) and galvanostatic cycling (CC) experiments.
The occurrence of Fe and Mn in the phospho-olivine and their influence on the cell performance will be discussed (cf. figure 2). Furthermore, Mg is incorporated into the lattice and its influence on electrochemical behavior will be shown as well (cf. figure 3).
Herbert Quandt Foundation is gratefully acknowledged for funding.
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