743
Enhancement of Platinum Mass Activity at Polymer-Wrapped Carbon Nanotube-Based Fuel Cell Electrocatalysts
Cost reduction and improved durability are the two major targets for accelerating the commercialization of PEFCs. To achieve these goals, the development of a novel method to fabricate platinum (Pt)-based electrocatalysts with a high mass activity, deposited on durable conductive support materials, is necessary.
In this study, we report a facile approach to grow homogeneously dispersed Pt nanoparticles (Pt) with a narrow diameter distribution in a highly controllable fashion on polymer-wrapped carbon nanotubes (CNTs)[8]. A PEFC cell employing a composite with the smallest Pt nanoparticle size (2.3 nm diameter) exhibited a ~8 times higher mass activity compared to a cell containing Pt with a 3.7 nm diameter. This is the first example of the diameter control of Pt on polymer-wrapped carbon supporting materials. using a minimal amount of Pt.
References
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[8] I. H. Hafez, M. R. Berber, T. Fujigaya, N. Nakashima, Scientific Reports, 2014, 4, art no.6295.