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Study of Morphological Variation on SiO2/Nafion Composite Membrane Under Different Hydration Condition
The performance of membrane electrode assembly (MEA) with SiO2/Nafion composite membrane is tested under different hydration and temperature conditions. For more detailed characterization, morphological variations of the composite membrane under hydration conditions are studied by using dynamic mode atomic force microscopy (DMAFM). DMAFM can map amplitude and phase distribution on the specimen surface. The phase lag, which is mechanical vibration changing of a cantilever, is resulting of tip-sample interaction, which is induced by microscopic mechanical property of sample. Thus, the DMAFM is best tool for characterizing heterogeneous materials such as composite membrane. The morphological structure variation on the composite membrane by water retention elevation is systematically studied by using phase lag changing under different humidification condition.
References
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Bella Nicotera, Apostolos Enotiadis, Kristina Angjeli, Luigi Coppola, Giuseppe A. Ranieri, and imitrios Gournis, Effective Improvement of Water-Retention in Nanocomposite embranes Using Novel Organo-Modified Clays as Fillers or High Temperature PEMFCs, Journal of Physical Chemistry B 115, (2011), 9087–9097