788
(Invited) Conjugated Polymer Spherical Microcavities for Energy Conversion

Sunday, 29 May 2016: 14:20
Aqua 314 (Hilton San Diego Bayfront)
Y. Yamamoto (University of Tsukuba)
Optical microcavities play an important role for the next-generation light technology. Recently, we succeeded in fabricating spherical microcavities from conjugated polymers (CPs) by simple self-assembly process and found that the microcavities show whispering gallery mode (WGM) resonant photoemission [1-4]. The CP-based microcavities are superior to conventional microcavities in points of simple fabrication process, function as both cavity and emitter, high photo-stability and optical gain, and potent use for electrically-driven WGM and lasers. In this presentation, we demonstrate the WGM-mediated intersphere light propagation and cascade-like energy conversion, in which the confined modes realize directional light energy transport between adjacent spheres and subsequent color conversion.

[1] T. Adachi et al., J. Am. Chem. Soc. 2013, 135, 870-876. [2] L. Tong et al., Polym. Chem. 2014, 5, 3583-3587. [3] K. Tabata et al., Sci. Rep. 2014, 4, 5902/1-5. [4] S. Kushida et al., Macromolecules 2015, 48, 3928-3933.