Carbon nanotubes by chemical vapor deposition (CVD) were directly grown on the carbon cloth to increase the surface area where the catalysts were deposited. And then, the catalysts were deposited on CNT by the electrochemical method, and finally did test and analyzed. The electrochemical characterizations were obtained by cyclic voltammetry (CV) in argon saturated 0.5M H2SO4, 0.5M H2SO4 + 1M CH3OH solution, respectively. The morphology of Pt/CNT/Carbon Cloth was observed by scanning electron microscope (SEM). The Pt loading was obtained by inductively coupled plasma mass spectrometry (ICP-MS). The results showed that the pulsed electrodeposition provided uniform distribution of catalysts ,and the peak power density of homemade Pt/CNT/CC as the anode of PEMFC increased by about 300 mW/cm2 compared to commercial Pt/CB/CC under the same conditions because of carbon nanotubes offering high surface area and having excellent electron conductivity.