In this study, deposition of metal catalysts on ZnO NR gas sensing devices was successfully conducted by the sputter method. Pd and Pt were selected as catalysts to improve the gas sensing behaviors such as gas response, gas response rate, and selectivity. The amount of 1 or 2 % of catalysts was deposited on the gas sensing devices. When metal catalysts were applied, operation temperature of ZnO NR gas sensors was successfully reduced from 300 °C to 100 °C. Moreover, enhancement in gas sensing behaviors was observed with catalysts but degraded gas sensing behavior occurred with large amount of the catalysts. Improvement was resulting from the increase in activate sites and modification of the Fermi energy level. The degradation was primarily due to the blockage of activate sites caused by excessive amounts of catalysts. Catalysts decorated ZnO NR gas sensors can be a candidate for lowered operating temperature with great gas responses.
This research was partially supported by the Korea Institute of Energy Technology Evaluation and Planning (20158520000210) grant funded by the Korea Government Ministry of Trade, Industry and Energy, a grant from a Strategic Research Project (2013-0132) funded by the Korea Institute of Construction Technology, and Auburn University IGP.
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