In this work, we first present a framework to determine the energy cost of a regenerative hydrogen fuel cell (RHFC) for storing electrical energy in hydrogen. We then evaluate the overall energy efficiency of using a RHFC to store intermittent (wind and solar) electricity, and compare to earlier results for various battery technologies. Although the round-trip efficiency of RHFC electricity storage (30%) that is less than half that of batteries, less energy is required to manufacture the RHFC system than a battery. The RHFC's lower manufacturing energy requirement offsets its larger efficiency losses as compared to batteries.
As a result, the RHFC system has a life-cycle energy efficiency as high as the most efficient batteries when storing wind power -- and considerably better than lower cost lead-acid batteries -- when considering both manufacturing and round-trip efficiency. The overall energy return on investment (EROI) of a storage-equipped wind farm using hydrogen storage would be significantly higher than one that uses lead-acid batteries (widely deployed for grid storage), and similar to lithium-ion batteries. However, the RHFC system is, overall, less efficienct than even the least efficient batteries when storing solar power. Its low round-trip efficiency significantly degrades the overall energy performance of the facility. In this application, battery technologies with higher round-trip efficiencies, such as lithium-ion batteries, are much more attractive.
To compare RHFC's to other storage technologies, we use the energy stored on invested (ESOIe) ratio: the ratio of energy stored in the device over its lifetime to the energy required to build and operate the device. A storage system with a higher ESOIe ratio provides at a lower cost of manufacturing energy, leaving the difference available for other productive uses. We considered a RHFC system that pairs an alkaline water electrolyzer with a PEM fuel cell. This hypothetical RHFC system has a more favorable ESOIe than the best battery technology (Li-ion, ESOIe = 35; Energy Env. Sci., 2015, 8, 1938), though still lower than those of pumped hydro (ESOIe = 1100) and compressed air (ESOIe = 830). We also present preliminary data on net energy values for RHFC systems based on solid oxide cells.