2008
Integrated-Evanescent Raman Sensors Based on Titanium-Dioxide Nanophotonics

Thursday, 2 June 2016: 11:40
Aqua 310 A (Hilton San Diego Bayfront)
C. C. Evans, C. Liu, and J. Suntivich (Cornell University)
The success of next-generation chemical monitoring and molecular identification technologies hinges on the ability to resolve between different chemical environments. Fully-integrated evanescent Raman spectrometers can provide this solution; however, current materials used in excitation and collection optics are limited to near-infrared wavelengths, which have reduced Raman cross-sections when compared to visible wavelengths, and are not compatible with visible lasers and detectors. Here, we show that titanium dioxide (TiO2) can serve a new material platform for evanescent Raman spectroscopy that can address these challenges. We experimentally show that visible TiO2 nanophotonics increases the internal efficiency of the Raman scattering by more than two orders of magnitude over previous reports. Our TiO2 nanophotonics demonstrate a material solution to the chemical sensing challenge and an opportunity to enhance future sensing functionalities of nanophotonics by innovating at the material level.