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(Invited) Phase-Field Method of Li Dendrite Formation during Electrodeposition

Tuesday, 31 May 2016: 08:30
Indigo 202 A (Hilton San Diego Bayfront)
L. Chen (Mississippi State University), Z. Liu (The Pennsylvania State University), Y. Qi (Michigan State University), P. Lu (General Motors R&D Center), and L. Q. Chen (The Pennsylvania State University)
The recent attempts to model the Li-dendrite formation using the phase-field method will be briefly reviewed.  In particular, a nonlinear phase-field model, accounting for the Butler-Volmer electrochemical reaction kinetics, will be presented. The dendritic patterns are examined as a function of applied voltage and initial electrode surface morphology. A design map is proposed to tailor the electrode surface morphology and the applied voltage to avoid undesired dendritic patterns. The possibility of incorporating the effect of SEI on the Li-dendrite formation in a phase-field model will be discussed.