2140
100k Cycles and Beyond: Extraordinary Stability for Au@MnO2 core@Shell nanowires Imparted By Gel Electrolyte

Tuesday, 31 May 2016: 14:30
Aqua Salon F (Hilton San Diego Bayfront)
M. Le Thai, R. M. Penner, and G. Thesma Chandran (University of California, Irvine)
Nanowire electrodes for batteries and super-capacitors can produce superior power relative to films of the same materials.  But the Achilles Heel of nanowires is their susceptibility to degradation and failure.  This is particularly true for materials that employ Faradaic reactions requiring ion insertion/deinsertion for energy storage.  Here we describe the preparation of arrays of ultra-long (2.5 mm) Gold@δ-MnO2, core@shell nanowires.  Gold@δ-MnO2 nanowires are prepared on glass surfaces using a variant of the Lithographically Patterned Nanowire Electrodeposition process.  All nanowire capacitors prpared from these ultra-long nanowires produce state-of-the-art metrics for energy and power in MnO2-based systems, but they demonstrate irreversible capacity loss exceeding 20% in ≈4000 - 8000 cycles.  This cycle stability nevertheless represents the state-of-the-art for MnO2 based electrodes.  Now we have discovered that the addition of poly(methylmethacrylate)(PMMA) to the propylene carbonate (PC) electrolyte extends cycle stability to 100,000 cycles and beyond.  Other energy storage metrics of these systems are not degraded by the PMMA.  In this talk, I describe the results of our experiments, and present data on the charactrerization of these Gold@δ-MnO2 nanowire systems in PC electrolyte and PC electrolyte containing PMMA, before and after cycling.