Electrodeposition of chalcogen alloy films under illumination can spontaneously generate nanopatterned films with significant periodic and multi-dimensional order. The feature sizes, periodicities, anisotropies, and orientations of the nanoscale pattern can be controlled by manipulating the input optical excitation. Isotropic morphologies consisting of ordered arrays of nanopores were generated using unpolarized illumination whereas linearly polarized light resulted in highly-anisotropic nanoridge/trough morphologies with the in-plane orientation of the patterns controlled by the direction of the light polarization. The pattern periodicity was encoded by the illumination spectral profile. A single periodicity in single spatial direction was only generated even with the use of broadband and multimodal spectral profiles and multiple polarization inputs and the periodicity was found to be sensitive to all investigated tuning of such profiles. Structures with nonequal periodicities in the two orthogonal in-plane directions could also be generated and both periodicities could be independently controlled. Overall structural complexity correlated could be scaled by increasing the complexity of the optical inputs. Modeling of the growth using a combination of full-wave electromagnetic simulations of light absorption and scattering coupled with Monte Carlo simulations of mass addition successfully reproduced the experimentally observed morphologies and indicated that morphology development was directed by evolution of the growth interface to maximize anisotropic light collection.