With the rising energy demand, safe and efficient energy storage technologies have been increasing in importance. Lithium-ion batteries (LIBs) have been dynamically prevalent as energy storage and power sources for various electrical systems, from communication purposes to transportation applications. Lithium Polymer (LiPo) batteries are a subcategory of LIBs that use a solid or semisolid (gel) polymer to act as both a separator and electrolyte for the system. Compared to a conventional liquid electrolyte, gel polymer electrolyte is more thermally and electrochemically stable and relatively safer. Various companies produce a vast number of different LiPo batteries; however, a limited number of studies have been conducted concerning modeling and simulation. Besides exploring new materials for performance enhancement, engineering a reliable model is equally vital to exploit and optimize existing LiPo batteries' potential.

In this study, a multiphysics model for a mobile Lithium Cobalt Oxide (LCO)-graphite- Poly(vinylidene fluoride - hexafluoropropylene) (PVdF-HFP) pouch LiPo battery was established to characterize the battery's behavior. The pseudo-2-dimensional electrochemical model and 3D thermal-thermal runaway model were coupled with temperature and heat generation variables. Working voltage and temperature during galvanostatic discharge were examined for the electrochemical-thermal model. In contrast, temperature as a function of time during an oven test was analyzed for thermal runaway models. The electrochemical-thermal and thermal runaway behavior was investigated using the simulation model, and validations were compared with experimental data. Overall, the models can be employed as a design tool to evaluate the component design and estimate the system performance of LiPo batteries for commercial applications.

KEYWORDS: Multiphysics model, Lithium-polymer battery, Thermal runaway