Tuesday, 31 May 2022: 09:10
West Meeting Room 208 (Vancouver Convention Center)
Molecular functional devices have been investigated through the study of molecular structure and its corresponding discrete orbital states since it determines the transport behaviors. [1,2] In contrast to the conventional strategy, we have demonstrated a novel strategy and design rule for realizing molecular-scale functions based on the energy band engineering in molecular heterojunction with two-dimensional (2D) semiconductors [3,4]. Recently, we have designed molecular heterojunction selector and the nonlinearity design rule with the role of the molecular dipole moment orientation which controls the band bending of the 2D semiconductor [4]. Likewise, various role of the molecular self-assembled monolayer (SAM) in hybrid heterostructure device with 2D semiconductor can give a novel and diverse functionality to the device that it can be a powerful platform for the next-generation functional devices. We implemented ferrocene substituted alkanethiol SAMs, which is a redox active molecule [5], in 2D MoS2 field-effect transistor (FET) structure. The redox state (oxidation or reduction) of the SAM is controlled through the gate bias and the oxidized molecular states (Fc -> Fc+) can act as a localized gate at the interface between molecule/2D semiconductor (MoS2) which the conductance of the n-type MoS2 channel can be modulated. This MoS2 FET with non-volatile multistate MoS2 channel can be suggested as electrochemically programmed molecular heterojunction artificial synapse.
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[2] H. Song, Y. Kim, Y. H. Jang, H. Jeong, M. A. Reed, T. Lee, Nature 462, 1039 (2009).
[3] J. Shin, S. Yang, Y. Jang, J. S. Eo, T.-W. Kim, T. Lee, C.-H. Lee, G. Wang, Nat. Commun. 11, 1 (2020).
[4] J. S. Eo, J. Shin, S. Yang, T. Jeon, J. Lee, S. Choi, C.-H. Lee, G. Wang, Adv. Sci. 2101390 (2021).
[5] Y. Zhao, S. Bertolazzi, M. S. Maglione, C. Rovira, M. Mas-Torrent, P. Samori, Adv. Mater. 32, 2000740 (2020).