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Cerium Oxide Electrochemical Formation Onto Al 6061 Using a Deep Eutectic Solvent

Wednesday, 1 June 2022
West Ballroom B/C/D (Vancouver Convention Center)
J. Aldana (Universidad Autónoma Metropolitana Azcapotzalco), A. V. Basilio Brito, D. Hernández (Universidad Autónoma Metropolitana), M. Romero-Romo (Universidad Autónoma Metropolitana (Azcapotzalco)), E. Arce-Estrada (ESIQIE-IPN), and M. E. Palomar Pardave (Universidad Autonoma Metropolitana)
In this work, a study of the electrodeposition of Ce onto an aluminum 6061 alloy was carried out from Ce salt dissolution in a deep eutectic solvent formed by choline chloride and ethylene glycol at 70 °C, to increase the alloy’s corrosion protection in saline media (3.5% NaCl). In order to corroborate the CeO2 deposit, a surface characterization was carried out by SEM, XPS and EDX, which corroborated the presence of 41.33% of Ce deposited on the Al alloy after applying a potential of -1.45 V for 3000 seconds. Electrochemical impedance spectroscopy (EIS) led to determining the corrosion resistance of the modified material and the corrosion inhibition efficiency of 92%, concerning the blank in 3.5% NaCl.