Pressurization of an SOFC can cause improvement on electrode kinetics, stack lifetime and round-trip efficiency by cell integration with downstream components such as gas turbines and catalytic reactors (for electrolysis) [1-4]. However, literature data from experimental studies on the electrochemical behavior of the SOFC as a function of operating pressure is relatively scarce. This is presumably due to the complexity involved in the construction and operation of pressurized system. To address such research challenge, a pressurized SOFC test rig as shown in Fig. 1 has been constructed and commissioned at Tennessee Technological University (TTU) to allow tubular SOFCs to be characterized under a maximum operating pressure of 60 psia (~4 bar) and maximum operating temperature of 825oC. A detailed system set-up shown in Fig. 2. The power generation capacity for the test rig can be scaled up to 2.4 kW. For this study, performance of single anode supported SOFC tubes with H2 and CH4 fuels were examined by varying pressure from 1 bara to 4 bara and temperature from 675oC to 775oC, with fuel utilization held constant at 50% and an oxygen-to-carbon ratio (O/C) of 0.6 for the methane operation. The testing cells were gratuitously supplied by Special Power Sources (SPS) LLC, USA, with cathode/electrolyte outside-layers supported on the anode inner-layer as a 14”-long tube. Silver ink and wires are used for cell current collection from active surface area of ⁓100 cm2. The connection fixture can be seen in Fig. 1. V-I curves of tubular SOFCs in Fig. 3 measured from step-wise electronic load profile indicate total performance gain of 13% as H2 pressure increases from 1 bara to 4 bara, with highest peak power density obtained at 0.61 Wcm-2. As comparison Fig.4 and 5 demonstrate pressurization suppressed gas diffusion limit for tubular SOFC at higher current density in CH4 fuel, leading to 44 % increase of peak power density to 0.51 Wcm-2 at 4 bara.
Electrochemical impedance spectroscopy (EIS) studies were performed using a Solartron 1260/PAR 263 electrochemical testing system in 4-point connection measurement to understand effects of pressurization on the SOFC performance. SOFC impedance spectra as Nyquist and Bode plots in Fig.6 (b) and (d) indicate the tubular SOFC performance is mainly limited by anode mass transports, which are greatly improved by pressurization. From non-linear, least-square cell impedance fitting and previous findings on impedance of similar larger cells, an equivalent-circuit model (ECM) in Fig. 6(a) has been identified to best represent impedance responses from the most rate-limiting processes of tubular SOFCs. The Warburg component (Ws) in the ECM with resonance frequency around 10Hz typically corresponds to gas diffusion in porous electrode of tubular SOFC [3-5], while paralleled R-CPE component at <1Hz resonance frequency can be attributed to gas-conversion impedance (GCI) due to gas phases concentration gradient along fuel-flow channel resulting from reactant conversion [5,6]. Experimentally observed changes of such impedances with fuel compositions, flow rates and tubular SOFC configuration are generally in agreement with theoretical assumptions and other reports [4-6]. Overall, results of this work demonstrate pressurization can effectively boost anode-supported SOFCs’ performance by overcoming fuel-side mass-transport limit associated with practical cell configuration and testing geometry. The experimental performance data collected can then be used to fit key constants and estimate parameters for numerical modeling of the SOFC system performance at elevated pressures.
References can be seen in the figure document.