The generation of energetic (hot) electrons and the photoheating are intrinsic properties of any optically excited plasmonic nanocrystal [1,2]. In addition, high-energy hot electrons and phototemperature contribute to the kinetic processes observed in plasmonic photodetectors, colloidal nanocrystals, and metastructures [1,2]. In this talk, we will focus on the theory of hot electron generation and present related applications for plasmonic photochemistry and plasmonic photocatalysis [3,4,5,6].

[1] L. Chang, L. V. Besteiro, J. Sun, E. Y. Santiago, S. K. Gray, Z. Wang, A. O. Govorov, ACS Energy Lett., 4, 10, 2552-2568 (2019).

[2] L. V. Besteiro, P. Yu, Z. Wang, A. W. Holleitner, G. V. Hartland, A. O. Govorov, Nano Today, 27, 120-145 (2019).

[3] T. Liu, L.V. Besteiro, T. Liedl, M.A. Correa-Duarte, Z. Wang, A. Govorov, Nano Letters, 19, 1395–1407 (2019).

[4] L. Khosravi Khorashad, L. V. Besteiro, M. A. Correa-Duarte, S. Burger, Z. M. Wang, A.O. Govorov, J. Am. Chem. Soc., 142, 9, 4193–4205 (2020).

[5] O. Ávalos-Ovando, L.V. Besteiro, A. Movsesyan, G. Markovich, T. Liedl, K. Martens, Zh. Wang, M.A.Correa-Duarte, and A.O. Govorov, Nano Letters (2021); DOI: 10.1021/acs.nanolett.1c02479.

[6] A. Movsesyan, E. Y. Santiago, S. Burger, M. A. Correa-Duarte, L. V. Besteiro, Zh. Wang, and A.O.Govorov, Advanced Optical Materials (2022); https://doi.org/10.1002/adom.202102663.