Thin-film glassy solid-state electrolytes (GSEs) are being considered for applications in energy storage devices; fully-dense thin-film glassy electrolyte materials are able to minimize power loss while suppressing dendrite growth. The glass with the composition Na₄P₂S_5.8O_0.92N_0.18 (NaPSON) was chosen because it balances the high conductivity of a sulfide chemistry with the high processability and electrochemical stability of an oxy-nitride chemistry. NaPSON thin-film GSE ribbons with thicknesses that range from 50 to 150 μm were drawn using a process of softening and drawing of a cast and annealed preform. Electrochemical impedance spectroscopy (EIS) was used on varying thicknesses of thin-film to investigate and compare the ionic conductivity of Na⁺ in the thin film compared to the bulk sample. Area specific resistance models as a function of time were created to compare the trend of bulk and interfacial resistances of different thicknesses. Thin-film samples were made into symmetric cells and cycled. The cycling of the symmetric cells gave insight into the behavior and durability of the electrolyte under applied voltage and sustained current. These results show that drawn thin-film electrolytes are a viable research direction for all solid-state batteries.