Tuesday, 11 October 2022: 14:40
Room 303 (The Hilton Atlanta)
Ion dynamics and charge transport in 1-methyl-3-octylimidazolium ionic liquids with chloride, bromide, tetrafluoroborate, tricyanomethanide, hexafluorophosphate, triflate, tetrachlorodialuminate, bis(trifluoromethylsulfonyl)imide, and heptachlorodialuminate anions are investigated by broadband dielectric spectroscopy, rheology and viscometry. A detailed analysis reveals anion and temperature-dependent separation of characteristic relaxation rates extracted from various representations of the dielectric spectra. The degree of separation is interpreted as an experimental signature of significant heterogeneity of the local ion dynamics associated with the structural glass transition, viscosity, and dc ion conductivity. It is found that the degree of dynamic heterogeneity correlates closely with the strengths of slow dielectric and mechanical relaxations previously attributed to the dynamics of mesoscale solvophobic aggregates. Increasing local dynamic heterogeneity correlates with an increase in the strength of the slow, aggregate dielectric relaxation and a decrease in the strength of the slow, aggregate mechanical relaxation. Accordingly, the local dynamic heterogeneity correlates with an increase in the static dielectric permittivities and a decrease in the contribution of aggregate dynamics to the zero-shear viscosities. These results are presented within a broader framework of current understanding of dynamics in ionic liquids and the interplay of dynamics, solvophobic aggregation, and charge transport in these technologically important systems.