Recently, great advance of the Li-S battery technology enables its penetration to the power source of the mid- and large-sized devices, which require high energy and power density that cannot be achieved in the Li-ion battery. While the most successful sulfur cathode could be designed by the optimization of the composite structure with carbonaceous materials, the binder system has been recently considered another important factor because the electrode structure of the sulfur cathode suffers huge structural change during the repeated electrochemical cycles. We studied the structural and electrochemical performance of the sulfur cathodes prepared by two different binders, the water-soluble SBR/CMC mixture binder and the traditional PVdF binder. The enhanced battery performance was observed in the SBR/CMC-based electrode and its origin was investigated by post mortem analysis about the electrodes, which confirmed the better mechanical integrity in the electrode compared with the PVdF-based electrode.