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V2O5-Based Composite As Mg-Ion Battery Electrode Material Studied By Electrochemical SPM at the Nanoscale
However, it is important to note that the research efforts dedicated to Mg-ion batteries are still in infancy. Recently, Gershinsky et al.6 explored that highly reversible Mg-ion insertion/extraction was possible with highly pure V2O5 thin-film electrodes using various electrochemical and spectroscopic analytical tools. A growing practical experience related to nanostructured materials suitable for Mg-ion battery applications requires a fundamental insight at nanoscale. In virtue of the Electrochemical Scanning Probe Microscopy (ECSPM) technique, especially Electrochemical Scanning Tunneling Microscopy (ECSTM), our approach to study magnesium intercalation is to use single-crystalline V2O5 to obtain an insight and accurate prediction of reaction mechanisms for the electrode of rechargeable Mg-ion batteries. In order to analyze the intercalation mechanisms of Mg2+, topographical changes of V2O5 will be analyzed under stepwise polarization to different potentials by ECSTM. The results will be described in terms of the combination among physicochemical phenomena, electrochemical metal-ion intercalation into single-crystalline host structures with different electrolyte systems, and electrochemical performance in rechargeable Mg-ion batteries. These studies will be complemented by three electrode electrochemical studies at nanostructured VOxcomposites, and compared to results obtained for Li-ion insertion.
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