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Lithium Phosphorous Sulfurous Oxynitride (LiPSON) as a New Solid Electrolyte Material for Application in Thin-Film Batteries and Electrochromic Devices
However, LiPON has a relatively poor ionic conductivity (< 1 x 10-6 S cm-1) and needs to be applied as a very thin film in order to obtain sufficient current densities in a cell rendering pin-hole free large-area deposition a major technological challenge. New materials with higher conductivities would be highly desirable.
Here, we report for the first time on the successful deposition of lithium phosphorous sulfurous oxynitride (LiPSON) thin films by RF magnetron sputtering from a mixed Li3PO4 and Li2SO4 target in reactive nitrogen atmosphere. The electrical properties (ionic and electronic partial conductivities) of the films have been characterized by electrochemical impedance spectroscopy (EIS) and DC polarization techniques. Ionic conductivities as high as 6 x 10-6 S cm-1 (Ea= 0.47 eV) are achieved. Moreover, we succeeded also in preparing pure LiPON films with extraordinary high ionic conductivities and high deposition rates. Our detailed analysis of the films includes the characterization of compositions by energy-dispersive X-ray spectroscopy (EDX) and by inductively coupled plasma optical emission spectrometry (ICP-OES) as well as of chemical properties by photoelectron spectroscopy (XPS). In addition, we characterized the optical properties of the films by UV-VIS spectroscopy.
Finally, we will present first results of the electrical properties of cathode/LiPSON half-cells.