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A Multi-Scale Computational Homogenization Formulation for Li-ion Battery Cells

Friday, 13 June 2014
Cernobbio Wing (Villa Erba)
A. Salvadori (Eindhoven University of Technology and University of Brescia), D. Grazioli (University of Brescia), and M. G. D. Geers (Eindhoven University of Technology)
In a recent contribution the Computational Homogenization technique was tailored to model the multi-physics processes that take place in Li-ion batteries. An improved formulation is presented here. Novelties incorporated are: i) electroneutrality - which is assumed (yet not imposed as for the balance equations); ii) Maxwells equations - considered in a quasi-static sense in a rigorous way; steady motion of charges is used for the mere estimation of the magnetizing field along the electrolyte/active particle interface; iii) time dependent scale transitions - formulated as required by the length/time scales involved in Li-ion batteries processes; iv) scale separation in time - a concurrent time modeling between the macro and micro scales is carried out. Preliminary numerical results of this multiscale approach are shown.