We have targeted MXenes as potential electrodes for sodium system. MXenes have been developed as a novel family of nanosheet compounds, which are chemically derived from layered Mn+1AXn or MAX phases (M: early transition metal, A: A-group element, and X: C and/or N). As the MXene has both a high electrical conductivity and interlayer porous space, its application to Na-ion battery negative electrodes holds great promise.
In this presentation, we report on Tin+1CnTx as negative electrode materials for Na-ion batteries. Tin+1CnTx consists of abundant and low-cost elements, enabling fabrication of sustainable energy sources. We demonstrate that Ti2CTx exhibits a reversible capacity of 175 mAh/g at the average potential of 1.3 V vs. Na/Na+. Furthermore, the prototype full cell consisting of alluaudite Na2Fe2(SO4)3-Ti2CTx delivers a high specific energy of 260 Wh/kg at a high specific power of 1.4 kW/kg based on the weight of Ti2CTx. Using various experimental and theoretical analyses, we clarify that the Tin+1CnTx electrodes allow Na-ion batteries to be liberated from the trade-off between high energy and high power.
[Reference]
X. Wang, et al., M. Okubo, & A. Yamada, Nat. Commun., 2015, 6, 6544.