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Mn3O4/CNT Nanocomposites Derived from Waste Manganese Resources As High Performance Anode Materials for Lithium Ion Batteries

Monday, 20 June 2016
Riverside Center (Hyatt Regency)

ABSTRACT WITHDRAWN

It is very important to explore cost-effective, high capacity and stable anode materials for lithium ion batteries from earth-abundant resources. Here we report a facile ball-milling method to prepare Mn3O4/CNT nanocomposites from some waste resources like  amorphous manganese oxide from recycled batteries or from electrolytic manganese industry. The obtained Mn3O4/CNT nanocomposites were intensively investigated as anode materials for lithium-ion batteries and supercapacitors. In these Mn3O4/CNTs nanocomposites with a unique bird nest architecture, the CNTs work as electrical wiring branch. This provides electron efficient transport pathway and accommodate a large volume change during the electrochemical reactions. While the ultrafine Mn3O4 nanoparticles grafted onto the CNTs ensure high specific capacity. Therefore, exceptional high capacity (>1000 mAh g-1) and extremely stable cycling were achieved.