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Advnaced Silicon and Tin Anodes for Lithium Ion Battery

Tuesday, 21 June 2016
Riverside Center (Hyatt Regency)
Z. Chen (University of Waterloo) and A. Yu (Univerisity of Waterloo)
Development of low cost, high energy, safe and long-life rechargeable battery technology is critical for widespread commercialization of smart grid and electric vehicle. Rechargeable lithium-ion batteries have been considered as most promising candidates as energy storage system for transportation, smart grids and stationary power. In this presentation, I will present our recent work on advanced Silicon(Si) and Tin(Sn) anode materials development for next generation rechargeable lithium-ion batteries: (1) The latest achievements and some ongoing work in silicon anode based high energy Li-ion battery through the collaboration with General Motors. More specifically, advanced Si electrodes have been developed by a simple flash heat treatment and sulfur-doped graphene wrapping technique which can efficiently accommodate Si volume expansion and demonstrate excellent electrochemical reversibility and cycling. (2) A novel and facile method was developed to synthesize a rod-on-sheet-like nanohybrid (denoted as SnS-SG), consisting of one-dimentional (1D) single-crystalline, orthorhombic tin sulfide (SnS) supported on two-dimentional (2D) sulfur-doped graphene. The SnS-SG nanohybrid exhibited a superior cycle stability over 1500 cycles with a high capacity retention of 85%, the longest demonstrated cyclability among numerous Sn-based anode materials reported so far in LIBs.