Since silicon provides a very high gravimetric and volumetric capacity, a low operation potential and low costs, it is widely regarded as the most promising anode material in LIBs for the future.[1] However, major issues arise from its poor capacity retention due to mechanical degradation caused by the large volume expansion during lithium insertion/extraction. In recent years, several attempts have been undertaken to overcome this problem.[2] Compared to bulk silicon anodes, which contain at least 10 wt.% of inactive binders and conductive additives, silicon thin film anodes contain no inactive materials, giving an increased specific capacity.[3]
In this work, silicon-carbon thin films have been prepared by magnetron sputtering. The silicon-carbon thin films have been prepared by alternatively sputtering layers of silicon and carbon (layered structure of silicon and carbon) or by co-sputtering silicon and carbon (mixed silicon-carbon layers). The characterization of the electrodes was performed by focused ion beam-scanning electron microscopy (FIB-SEM), Raman spectroscopy and electrochemical impedance spectroscopy. Furthermore, the influence of the carbon content and layered/non-layered silicon-carbon structure was thoroughly investigated in cycling experiments compared to the bare thin film silicon electrodes.
Literature:
[1] R. Wagner, N. Preschitschek, S. Passerini, J. Leker, M. Winter, J Appl Electrochem. 43 (2013) 481-496.
[2] M.N. Obrovac, L.J. Krause, J Electrochem Soc. 154 (2007) A103-A108.
[3] U. Kasavajjula, C. Wang, A.J. Appleby, J Power Sources, 163 (2007) 1003-1039.