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Robust Ni-based Anode Deposited with La0.6Sr0.4FeO3-δ for Direct Methane-Fueled SOFCs

Monday, 24 July 2017
Grand Ballroom East (The Diplomat Beach Resort)
Y. Zhang, H. Fan, and M. Han (Department of Thermal Engineering, Tsinghua University)
Conventional Ni-YSZ anodes suffer from carbon deposition when methane is used in SOFCs as fuel. In this work, a new strategy was proposed to solve the problem, that the anode was modified by SrFe1.5Mo0.5O3 nanoparticles using infiltration method. It was found that, when humidified CH4 was used as fuels, SFM@Ni-YSZ anode-supported cell shows lower power output compared with the Ni-YSZ anode-support cell. However, the infiltrated SFM has a positive impact on the long term stability of the anode. No significant degradation was found in 100hrs operation at 0.15A/cm2 and 750oC, indicating the excellent carbon deposition resistance of SFM@Ni-YSZ anode. Furthermore, it was found that the amount of infiltrated SFM was related to the anode performance, which gives a way to gain a compromise between SOFC performance and carbon deposition resistance.