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Electrochemical Analysis and Interfacial Stability of Carbon-Overlay LiNi0.5Mn­1.5O4 Cathode Material for High Potential Lithium Ion Battery

Wednesday, May 14, 2014
Grand Foyer, Lobby Level (Hilton Orlando Bonnet Creek)
Y. C. Jin and J. G. Duh (Department of Materials Science and Engineering, National Tsing Hua University)
Recently, researches in lithium ion battery have focused on interfacial properties of various cathode materials. The interfacial reaction on the electrode material greatly dominates its electrochemical performances and thermal stability, especially manganese-type spinels. The deteriorated cyclability of LiNi0.5Mn­1.5O4cathode at elevated temperature greatly hinders its realistic applications. One of the reasons is that the high surface reactivity with the electrolyte at an ultimate operating voltage around 4.7V, associating with the dissolution of Mn and the formation of SEI layer.

A proper SEI-layer can not only facilitate lithium intercalations but also provides a good protection from the undesired electrolyte invasion. This study demonstrates the carbon-overlay on the surface of LiNi0.5Mn­1.5O4 electrode through atmosphere-controlled sputter techniques. The advantage of sputtered carbon layer on the electrode surface is without the degrading of pristine spinel structure. The carbon-overlay with the appropriated thickness was found to extend the cycle life and suppress the swelling behavior of LiNi0.5Mn­1.5O4 cathode material. The essential benefits of carbon-overlay is to stable the SEI layer on LiNi0.5Mn1.5O4 cathodes, retarding the severe capacity decay at elevated temperatures. Charge transfer kinetics and failure mechanisms involving the high-voltage oxidation and high temperature degradation are also detailed discussed.