Transition metal catalysts supported on metal-oxide surfaces are promising materials for usage in heterogeneous catalysis due to strong metal-support interaction, which affects the intrinsic activity at the surface, and results in enhanced dispersion of metal atoms in some cases, thus promoting stability. One of the most widely investigated such systems are Pt/CeO2
systems, which have been found to be highly active toward the water gas shift reaction . Experimental and theoretical studies point to electron and oxygen transfer between adsorbed Pt atoms and CeO2
support as the reason for the enhanced activity in such systems [2, 3]. The effect of this metal-support interaction, however, is far from clear in context of the redox reactions that occur in DMFCs and PEMFCs. Especially, the role of CeO2
, well known for its oxygen storage capacity, remains yet to be investigated in co-catalysis. To this end, understanding and characterizing the dispersion of Pt on the CeO2
surface is of utmost importance. Stability and activity of a few Pt layers on rutile metal-oxides has been investigated computationally, yielding insights into the geometric and electronic influences of the support on the catalyst . Sub-monolayer deposition of catalyst atoms opens up the support surface to direct engagement with the reactants and is well worth investigating. In this study, first principles DFT calculations are used in combination with rigorous statistical mechanics methods to find stable phases of Pt atoms dispersed on the CeO2
(111) surface as a function of their chemical potential. Employing the Cluster Expansion formalism in tandem with the Metropolis Monte Carlo Method to account for the configurational contribution to the system’s free energy , the important interactions dictating the surface morphology are identified. In agreement with experiments , a remarkable transfer of oxygen from CeO2
to the Pt atoms is observed, and a tendency of Pt atoms to aggregate at low surface coverage is also seen. Further, using a linear Gibbs energy relation, the energetics of various reaction steps in a 2 e- oxygen reduction (ORR) process of the Pt/CeO2
system are computed for several instances of oxygen co-adsorption and are compared to those of a model Pt (111) system as a function of the electrode potential. Additionally, the effect of support on the dissolution potential of Pt atoms is also evaluated to understand the stabilizing effect of the support, which has been observed experimentally . Enhancement in ORR kinetics for Pt/CeO2
systems has been observed experimentally, but such studies are few . Two mechanisms are proposed in this study to explain such a behavior: (1) the preferential adsorption of OH on only Pt in contrast to the co-adsorption of O on both Pt and CeO2
, and (2) the activation of O-O bond breaking due to the oxygen starved CeO2
surface. In principle, such systems with the possibility for the support material to take part in the reaction along with the catalyst atoms can open up new channels that facilitate ORR.
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