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Simple Patterning of Large-Area Graphene By Metal Mask and Sacrificial Polymer Layer
In this work, we report a new approach for a simple patterning of graphene film by metal mask using a sacrificial methyl methacrylate (PMMA) polymer layer. Our method includes both spin-coated polymer layer as sacrificial layer and metal deposition by shadow mask as etching mask. After the graphene is placed on Si substrate, PMMA layer is spin-coated on top of the graphene film, and then the metal is evaporated through shadow mask. After the samples are exposed under plasma etching, the patterned graphene is obtained. The metal is then easily removed along with the with the PMMA layer by a acetone lift off. The size and shape of patterned graphene is the exactly same as the metal mask. We show that this new method can apply to different types of graphene film such as chemical vapor deposition (CVD) graphene and reduced graphene oxide (RGO) demonstrating as a reliable processing technique. In contrast to conventional metal etch mask patterning, our method does not include any harmful acid treatment of removing metal mask, making it an environmental-friendly method. We also fabricated OFETs by thermally depositing pentacene using patterned graphene electrode. Our devices show excellent device performance with a maximum mobility of 0.33cm2/Vs and current on-off ratio of ~105. We believe that this approach can open the new pathway for manufacturing other carbon-based thin film devices.