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Non-Paste Based Composite Cathode Electrode for Lithium Air Battery

Wednesday, May 14, 2014: 11:10
Bonnet Creek Ballroom III, Lobby Level (Hilton Orlando Bonnet Creek)
J. Kosivi (Florida A&M University), J. Gomez (Department of Chemical & Nuclear Engineering, University of New Mexico), R. Nelson (Department of Electrical and Computer Engineering, Florida A&M University - Florida State University College of Engineering, Tallahassee, FL 32310), E. E. Kalu (Florida A&M University - Florida State University College of Engineering), and M. H. Weatherspoon (Department of Electrical and Computer Engineering, Florida A&M University - Florida State University College of Engineering, Tallahassee, FL 32310)
Lithium air batteries have remarkable high theoretical energy density of about 12 kW·h/kg (43.2 MJ/kg) excluding the oxygen mass. However there are many short comings from its efficiency including limitations due to the use of binders. Non-paste based cathode electrode fabricated without the use of binders is explored for application in a Li-air cell.  Electroless-electrolytic nickel-molybdenum oxide deposited on a porous carbon substrate was evaluated as the oxygen reducing cathode elctrocatalyst in a Li-air cell. Results will be presented on the cycling data obtained using an electrolyte containing 1 M LiPF6 and DMSO. Cell performance shows good stability for the reduced oxygen species (superoxide) O2 ion.