Morphology Progression of Electrodeposited Li2O2 during Charging of Li/O2 Batteries
During charge, the amount of energy necessary to decompose Li2O2 likely depends on the morphology of the Li2O2 particles deposited3-5: higher surface energy morphologies should require less energy. The morphology formed on discharge depends heavily on cell potential with higher energy particles formed at higher overpotentials.4,5 Observing how Li2O2 is consumed during charge could further explain the relationship between cell overpotentials and Li2O2 morphology, as well as probe any differences in the discharge and charge mechanisms.
In this talk we will show how the morphology of electrochemically deposited Li2O2 changes at intermediate states of charge in a Li/O2 cell. Cells are discharged and charged at constant rate of 0.5 mAcm–2 as described in a previous report.5 After discharge is complete, various intermediate states of charge are sampled by stopping the charge at cell potentials of 3, 3.375, 3.75, 4.125, and 4.5 V. Partially cycled electrodes are harvested from the cell and imaged with scanning electron microscopy.
Figure 1 shows a typical discharge charge curve, with an image of a control electrode and the morphologies observed for a fully discharged cell and a cell charged to 4.5 V (coincidentally corresponding to about half of the discharge current). From this it is clear that Li2O2 is not consumed uniformly throughout the electrode during charge. The implications of the non-uniform consumption of Li2O2 for electron and O2 transport in the electrode during charge will be discussed.