The test patterns are manufactured on 300mm-diameter wafer by 65-nm 1-poly 7-metal standard CMOS technology. After polysilicon re-oxidation to form oxide film on polysilicon surface, the wafers are annealed at 800oC, 900oC, 950oC and 1000oC in N2ambient, respectively. Fig. 1 shows the process flow and annealing process steps in the flow. After anneal, the polysilicon grain size is measured by X-ray powder diffraction (XRD). And the electric characteristics for NMOS, PMOS and polysilicon resistance are tested.
Fig. 2 shows the poly resistance reduction proportion and poly grain size after anneal at 800oC, 900oC, and 1000oC for 5min, and 950oC for 20min in N2 ambient, respectively. Only after annealing at 950oC or above for 5min, the resistance can be obviously reduced, due to the poly grain size increasing. Fig. 3 shows threshold voltages (Vt) variation proportions of NMOS and PMOS owning gate length of 65nm and width 0.12µm after utilizing annealing process at different temperatures. PMOS is more sensitive to the anneal process than NMOS. But after anneal at 950oC or below, the threshold variation for both NMOS and PMOS is less than 5%, which is acceptable for the integration process manufacturing.
A new anneal process at N2 ambient to adjust the polysilicon resistance has been proposed. It has been verified that utilizing anneal process at 950oC or below, the 65nm MOS performances can be maintained almost same as before. Consequently, it is considered that the anneal method can be to be applied to the deep submicron integration process.
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