In this study, carbon-based non-precious metal catalysts (Me-N-C) were synthesized by impregnating aniline and different metal salts into a carbon matrix and pyrolyzing at 900℃ in N2 atmosphere.5, 6 The structure of obtained composites were characterized by X-ray photoelectron spectroscopy, Raman spectroscopy and X-ray diffraction. Their hydrogen evolution reaction (HER) activities were investigated in both 0.5 M H2SO4and 1 M KOH. For the first time, these non-precious metal electrocatalysts showed excellent activity for HER and good stability in both acidic and alkaline media. The Ni-C-N catalyst had the lowest onset potential while Co, Fe-C-N catalysts had smaller Tafel slopes than the former (Figure 1a).
Various active sites could contribute to the HER activity in Me-N-C catalysts (Figure 1b). Density functional theory (DFT) calculations were employed to understand the activity enhancement mechanisms and identify the active center. This work paved a new route in the design of cheap, robust and high efficient catalysts to replace Pt.
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