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Focused Ion Beam Reduced Graphene Oxide Micro-Supercapacitors with Unprecedented Energy and Power Densitites

Monday, 30 May 2016: 11:20
Indigo Ballroom A (Hilton San Diego Bayfront)
P. Chakraborty Banerjee, D. L. Lobo (Monash University), C. Easton (CSIRO), and M. Majumder (Monash University)
Miniaturization of energy storage devices with high energy and power densities can reduce the footprint of micro-devices being used in our daily life. Micro-supercapacitors with planar geometries offer several advantages, such as, the ability to control and reduce the distances ions travel between two electrodes, easy integration to micro devices as the separator and the electrodes are in the same plane, and offer the potential of being extended into 3D without compromising the inter-electrode separation distances. In this study, we have used focused ion beam technology (which is capable of producing reduced graphene oxide patterns and complex shapes in insulating films of graphene oxide with a possible spatial resolution down to ~20 nm in a mask-less and direct write approach) to directly write miniaturized planar electrodes of reduced graphene oxide on films of graphene oxide (GO).  We have optimised the ion-beam irradiation and have investigated the influence of ion beam irradiation on the resultant microstructure and the electrochemical properties of the resultant reduced graphene oxide films. Subsequently, using the optimized ion-beam irradiation, interdigitated electrode designs (40 μm long and 3.5 μm wide fingers with ultra-small inter-electrode spacing of 1 μm) have been generated, which have demonstrated a large capacitance (102 mF/cm2), ultra-small time response (0.03 ms), low equivalent series resistance (0.35 mΩ cm2), and have retained 95 % of the specific capacitance after 1000 cycles at an ultrahigh current density of 45 mA/cm2.  These performance metrics show unprecedented improvements on several aspects of supercapacitor performance over existing reports due to the miniaturized electrode dimensions and minimal damage to the graphene sheets. We believe our results can provide opportunities for large-scale fabrication of arrayed, planar, high performance micro-supercapacitors with a small environmental footprint.