Large scale, high quality growth of graphene has been enabled by successful application of vapor deposition techniques such as chemical vapor deposition (CVD). In extending the quest for high quality, large scale synthesis of 2D TMDCs, similar vapor deposition techniques have been explored, mainly CVD. Yet, high quality extended 2D TMDCs are still lacking.
Atomic Layer Deposition (ALD) can be instrumental to the production of large area, two-dimensional materials, and simultaneously offer superior alternatives to exfoliating methods. In this work we consider the transition metal dichalcogenide MoS2 – specifically its growth starting from an ALD route comprised of (tBuN)2(NMe2)2Mo and O3 to produce MoO3, followed by subsequent sulfurization steps to produce MoS2. Data from a variety of direct measurement techniques, including atomic force microscopy, x-ray photoelectron spectroscopy, Raman spectroscopy, and photoluminescence spectroscopy, for determining the existence and optical properties of monolayer MoS2 will be presented.