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Carbon Based Polymer Nanocomposites for Strain Sensor Applications

Tuesday, 3 October 2017: 10:00
Chesapeake K (Gaylord National Resort and Convention Center)
H. Liu (University of Tennessee, Knoxville, Zhengzhou University), K. Dai, C. Liu (Zhengzhou University), J. Guo (University of Tennessee Knoxville), L. Wu, M. Zhao (Shandong University), and Z. Guo (University of Tennessee Knoxville)
Strain sensors based on the resistance change upon exposing to mechanical deformation have been drawn great interests owing to their wide applications including health monitoring, movement detection and structural health monitoring. Recently, conductive polymer composites (CPCs) based strain sensors have attracted attentions due to their quick response in the form of electrical resistance variation when subjected to tensile strain. In this work, two dimensional graphene was used as electrical conductive filler to fabricate thermoplastic polyurethane based strain sensor. Compared with other carbon based electrical conductive fillers, such as one dimensional carbon nanotube and zero dimensional carbon black, graphene possesses superior mechanical flexibility, high restorability and carrier mobility, which enable its application in highly sensitive strain sensors with good reproducibility. The effects of filler loading, strain amplitude and strain rate on the strain sensing behaviors were studied systematically. Wide range of strain sensitivity (gauge factor ranging from 0.78 for TPU with 0.6 wt% graphene at the strain rate of 0.1 min-1 to 17.7 for TPU with 0.2 wt% graphene at the strain rate of 0.3 min-1) and good sensing stability for different strain patterns were obtained. The CPCs also demonstrated good recoverability and reproducibility after stabilization by cyclic loading. This study provides a guideline for the fabrication of graphene based polymer strain sensors.

References:

1) Strain sensing behaviors of epoxy nanocomposites with carbon nanotubes under cyclic deformation, X. Cao, X. Wei, G. Li, C. Hu, K. Dai, J. Guo, G. Zheng, C. Liu, C. Shen, and Z. Guo, Polymer, 112, 1-9 (2017) Link to publisher; pdf file

2) Comparative assessment of the strain-sensing behaviors in polylactic acid nanocomposites: reduced graphene oxide or carbon nanotubes, C. Hu, Z. Li, J. Gao, K. Dai, G. Zheng, C. Liu, C. Shen, H. Song and Z. Guo, Journal of Materials Chemistry C, 5, 2318-2328 (2017) Link to publisher; pdf file.

3) Lightweight Conductive Graphene/Thermoplastic Polyurethane Foams with Ultrahigh Compressibility for Piezoresistive Sensing, H. Liu, M. Dong, W. Huang, J. Gao, K. Dai, J. Guo, G. Zheng, C. Liu, C. Shen and Z. Guo, Journal of Materials Chemistry C, 5, 73-83 (2017) Link to publisher; pdf file

4) Electrically Conductive Strain Sensing Polyurethane Nanocomposites with Synergistic Carbon Nanotubes and Graphene Bifillers, H. Liu, J. Gao, W. Huang, K. Dai, G. Zheng, C. Liu, C. Shen, X. Yan, J. Guo and Z. Guo, Nanoscale, 8, 12977-12989 (2016) Link to publisher; pdf file

5) Carbon Nanotubes-Adsorbed Electrospun PA66 Nanofiber Bundles with Improved Conductivity and Robust Flexibility, X. Guan, G. Zheng, K. Dai, C. Liu, X. Yan, C. Shen, and Z. Guo, ACS Applied Materials & Interfaces, 8(22), 14150-14159 (2016) Link to publisher; pdf file

6) Organic Vapor Sensing Behaviors of Conductive Thermoplastic Polyurethane-Graphene Nanocomposites, H. Liu, W. Huang, X. Yang, K. Dai, G. Zheng, C. Liu, C. Shen, X. Yan, J. Guo, Z. Guo, Journal of Materials Chemistry C, 4, 4459-4469 (2016) Link to publisher; pdf file

7) Electrically Conductive Thermoplastic Elastomer Nanocomposites at Ultralow Graphene Loading Levels for Strain Sensor Applications, H. Liu, Y. Li, K. Dai, G. Zheng, C. Liu, C. Shen, X. Yan, J. Guo and Z. Guo, Journal of Materials Chemistry C/em><, 4, 157-166 (2016) Link to publisher; pdf file

8) Strain Sensing Elastomer/Carbon Nanofibers "Metacomposites"; J. Zhu, S. Wei, J. Ryu and Z. Guo; Journal of Physical Chemistry C, 115(27), 13215-13222 (2011) pdf