Tuesday, 15 May 2018: 08:30
Room 212 (Washington State Convention Center)
PEM fuel cells are expected to play dominant role in future clean energy solutions for various applications. Developing highly efficient low-Pt and Pt-free catalysts are the key solutions for the wide-spread commercialization of PEMFCs. Through green chemistry and/or ALD techniques, we fabricated various novel Pt nanostructures, including nanowires, nanotubes, and single atoms. Compared to the conventional Pt nanoparticle/C commercial catalyst, these novel Pt nanostructures exhibited much enhanced activity (up to 10 times) and stability (up to 6 times) for fuel cells [1-7]. On the other hand, we recently developed novel Fe/N/C catalysts which exhibited higher activity in alkaline media and equivalent activity in acidic electrolyte compared to Pt. [8] Moreover, we systematically studied the decay mechanism of the MOF-based Fe/N/C catalyst, which is of significant important to improve the durability of Fe/N/C catalysts [9].
Both lithium-ion (LIB) and sodium-ion batteries (SIB) are promising technologies for energy storage. We developed a facile, inexpensive and scalable wet-chemical strategy to fabricate the Fe3O4/graphene composites and porous carbon spheres. The nanocomposite shows dramatically enhanced electrochemical properties including excellent reversible capacity, cyclability and rate performance in LIBs and SIBs [10,11].
References:
- Sun, et al., Angew. Chem. Int. Ed., 50, 422 (2011). (VIP+ Cover).
- Sun, et al., Adv. Mater., 20, 571(2008).
- Sun, et al., Adv. Mater., 20, 3900 (2008).
- Sun, et al., Chem. Mater., 19, 6376 (2008).
- Sun, et al., Chem. Commun., 45, 7048 (2009).
- Sun, et al., Chemistry-A European Journal, 16, 829 (2010). (Inside Cover).
- Zhang, et al., Scientific Reports, 3: 526 | (2013).
- Li, et al., Advanced Functional Materials (2016).
- Zhang, G, et al., Nano Energy, 2 (2016).
- Fu, et al., J. Mater. Chem. A, 3, 13807 (2015).
- Y. Fu, et al., RSC Advance. 6, 84149 (2016).