In the present work it is demonstrated (based on e.g. elemental analyses of cycled Sn, Al and Si electrodes) that lithium trapping can account for the capacity losses seen when alloy forming anode materials are cycled versus lithium electrodes, see Figure 1. It is shown that small amounts of elemental lithium are trapped within the electrode material during the cycling as a result of a two-way diffusion process [8] causing the lithium to move into the bulk material even during the delithiation step. This phenomenon, which can be explained by the lithium concentration profiles in the electrodes, makes a complete delithiation process very time consuming. As a result of the lithium trapping effect, the lithium concentration in the electrode increases continuously during the cycling. The experimental results also show that a similar effect can be seen also for commonly used current collector metals such as Cu, Ni and Ti. The latter means that these metals are unsuitable as current collector materials for lithium alloy forming materials in the absence of a thin layer of boron doped diamond serving as a lithium diffusion barrier layer [8].
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