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Phase-Field Simulation of Stress Evolution in Sodium Ion Battery Electrode Particles

Tuesday, 15 May 2018
Ballroom 6ABC (Washington State Convention Center)
T. Zhang and M. Kamlah (Karlsruhe Institute of Technology)
Sodium-ion batteries have been considered as a promising alternative to Lithium-ion batteries. The cathode material NaxFePO4 of sodium-ion batteries shows phase changes during intercalation. In this work, a phase-field model for NaxFePO4 is studied for the first time. A coupled phase-field model for the Cahn-Hilliard diffusion equation and finite deformation elasticity is derived. For the mechanical part, two finite deformation elasticity formulations based on elastic Green strain and logarithmic elastic strain, respectively, are introduced and compared. The material parameters for NaxFePO4 are determined. We implemented the model in COMSOL Multiphysics® for a spherically symmetric problem of sodium insertion into a cathodic particle made of NaxFePO4. Furthermore, we compare the two cathode materials NaxFePO4 and LixFePO4 to each other in terms of phase changes and stresses, and show that the stresses in the cathode material NaxFePO4 are larger at the phase segregated state.