The reported flexible RF transistors based on Si and GaAs thin film have shown the capability of working at the GHz range. However, due to a small bandgap and low breakdown field, they are not suitable for high power applications at high frequency. GaN has been rapidly developed for high-frequency and high-power applications due to its large bandgap, high breakdown field, high electron mobility, and high electron saturation velocity of two dimensional electron gas (2DEG). Several flexible AlGaN/GaN HEMTs have been fabricated by the transfer printing AlGaN/GaN thin film to flexible substrate. Our group have reported flexible RF AlGaN/GaN HEMT on PET substrate with an fT of 60 GHz and fmax of 115 GHz. A layer of 3.5 µm intrinsic single crystalline GaN thin film was used as the heat spreading layer for the HEMT due to large thermal conductivity of single crystalline GaN. The HEMT can successfully work under 0.5 W, which indicates the potential use of AlGaN/GaN HEMTs in high-frequency and high-power flexible electronics. We further combined flexible RF AlGaN/GaN HEMTs with environmental friendly green flexible substrates to fabricate flexible green RF electronics for high-power applications. We successfully fabricated a 500 µm × 500 µm AlGaN/GaN HEMT on biodegradable CNF substrate using the transfer printing technique. The HEMT can achieve an fT and fmax of 40 GHz and 79 GHz, respectively, and work under 0.3 W on CNF substrate. To further exploit the application of flexible green RF AlGaN/GaN HEMTs, we fabricated a flexible RF power amplifier based on the HEMT. The RF power amplifier was fabricated by combining the flexible HEMT and impedance matching network consisting of a spiral inductor and metal-insulator-metal (MIM) capacitor on a temporary Si substrate with a PMMA sacrificial layer. After dissolving the PMMA sacrificial layer, the entire RF power amplifier (~10 µm thick) was transfer printed on a CNF substrate. The RF power amplifier on CNF substrate shows a small signal gain of ~6 dB from 5 GHz to 6 GHz. The RF power performance measurement shows it can deliver an RF power of ~10 mW with peak power added efficiency (PAE) of 4% at 5.5 GHz. The recent progress of flexible RF AlGaN/GaN HEMTs and RF power amplifiers will significantly advance the development of flexible electronics for high-frequency and high-power applications.