Figure1a shows the cycling performance and coulombic efficiency of Zn plating and stripping on carbon film at a current density of 1mA cm-2 with an areal capacity of 1mAh cm-2. During each cycle, Zn is deposited on the carbon film at 1 mA cm-2 for 1 h and then stripped at 1 mA cm-2 until the potential reaching 0.5 V (vs. Zn2+/Zn). The coulombic efficiency is defined as the ratio of Zn removed from carbon film to that deposited during the same cycle. As can be seen, Zn can be stable deposited on and stripped from the carbon film within 100 cycles without short circuit. The initial coulombic efficiency of is 92.6% but it quickly roses up to 97.3% in the 3rd cycle and is stabled over 97% within 100 cycles. Moreover, from the plating and stripping profiles of Zn in Figure 1b, the potential hysteresis (defined as the difference of stripping/plating average potential in the same cycle) between the plating and stripping is less than 200 mV, indicating a fast electrochemical reaction kinetics. This result demonstrates that this low cost, fast kinetics and high efficiency carbon film shows potential as current collector for aqueous zinc-based batteries.
Acknowledges: The authors greatly acknowledge the financial support from National Natural Science Foundation of China (No. 51622703), and the National Thousand Talents Program of China.
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