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Highly Conductive and Stable Graphene/PEDOT:PSS Composites As Metal Free Cathodes for Organic Dye-Sensitized Solar Cells

Tuesday, 15 May 2018
Ballroom 6ABC (Washington State Convention Center)
J. C. Kim (Dongguk University), M. J. Ju (UNIST), M. M. Rahman (Konkuk University), K. Yoo, and J. J. Lee (Dongguk University)
Graphene is a potential candidate as a counter electrode (CE) material to replace the Pt for long-term stability and low-cost fabrication of dye-sensitized solar cells (DSSC). Although the catalytic activity of graphene towards iodine-based redox mediator is not significantly high, it exhibited excellent electrocatalytic activity for cobalt-based redox mediators. However, the low adhesion capacity of graphene with FTO and low stability is the significant problems of graphene based CE for the development of long-term stable DSSCs. This research demonstrated the fabrication of highly stable with strong adhesion capacity based graphene nanoplatelets (GnP) CEs for organic DSSCs. We used conducting polymer (PEDOT:PSS) together with GnPs to improve the adhesion, stability, and catalytic activity. Different weight percent (%) of GnPs were mixed with PEDOT:PSS (PP), and subsequently dispersed by ultrasonication. The dispersed solutions were deposited on FTO by an electro spray (e-spray) method and their electro-catalytic properties were measured for Co(bpy)32+/3+ redox couple (bpy=2,2′-bipyridine). The optimal PP/GnP (PPG) CE with 1wt% GnP mixed PP exhibited the profound improvement in conductivity, eletrocatalytic activity, and electrochemical stability for the Co(bpy)32+/3+ redox couple compared to the Pt, GnP, and PP CEs. The charge transfer resistance (RCT) of the optimal PPG CE at the CE/electrolyte interface was 0.07 W.cm2, which is much lower than that of Pt CE (1.02 W.cm2). Moreover, the optimal PPG CEs showed better electrochemical stability under prolonged potential cycling. The DSSCs based on the Y123 sensitizer and optimal PPG CE showed a higher photovoltaic performance (Jsc, FF, and h of 13.64 mA/cm2, 67.01%, and 8.33%, respectively) than those of Pt-CE (Jsc, FF, and h of 13.27 mA/cm2, 65.52%, and 7.99%, respectively), GnP-CE (Jsc, FF, and h of 12.74 mA/cm2, 65.69%, and 7.61%, respectively), and PP-CE (Jsc, FF, and h of 12.27 mA/cm2, 60.72%, and 7.03%, respectively).