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Intermediate Temperature Na-ZnCl2 Battery

Wednesday, 16 May 2018: 16:40
Room 604 (Washington State Convention Center)
X. Lu, H. J. Chang, J. F. Bonnett, N. L. Canfield (Pacific Northwest National Laboratory), K. Jung (Research Institute of Industrial Science and Technology), V. Sprenkle, and G. Li (Pacific Northwest National Laboratory)
Sodium-metal halide (Na-MH) batteries have been considered as one of the most attractive energy storage systems for stationary applications. Significant progress has been achieved in the Na-MH technologies during the past a few of decades. However, the batteries are still facing challenges in battery performance and cost. Recently, we have been working on advanced planar type Na-MH batteries with operating temperatures below 200oC. It was found that the low-temperature operation dramatically improved the battery performance (e.g., cycle life). Meanwhile, we have put efforts to replace the major cathode component of Ni in the Na-NiCl2 chemistry with Zn, which potentially can cut down around 46 and 20% of the cell material and overall battery costs. In this study, we further investigated the performance of the Na-ZnCl2 battery at intermediate-temperatures (e.g., 190oC). It was found the Na-ZnCl2 chemistry has significant higher rate capability over the Na-NiCl2 counterpart under similar operating conditions. The mechanisms for the higher rate capability could be related to the improved mass or charge transfer rate in the Na-ZnCl2 cathode. We believe this high-performance, low-cost, and safe Na-ZnCl2 battery will bring it one-step closer for broad market penetration of the Na-MH technologies.