Ion mobility data will be discussed in light of solvent uptake. As an example, Figure. 1 shows the relationship between the degree of solvation and relative quantity of deuterated acetonitrile solvating tetrabutylammonium (TBA) form 825EW 3M PFSA. The degree of solvation was derived from solvation signal picked up from carbon-13 NMR on cyanide carbon of deuterated acetonitrile. The degree of solvation increased accordingly with the amount of solvent until it reaches saturation when excess solvent molecules would not participate in the solvation. The respective diffusion coefficients from NMR pulsed gradient diffusion experiments on cations were also presented. A clear signal corresponding to solvent molecules involved in solvation is captured by FTIR and this will also be analyzed as a function of composition and ion type.
Acknowledgement
We gratefully acknowledge the support of this work by the U.S. Department of Energy, Office of Electricity Delivery and Energy Reliability (Dr. Imre Gyuk). We also thank 3M for providing membranes.
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Figure 1. Degree of solvated CN vs relative acetonitrile quantity of TBA+ form 825EW 3M membrane in deuterated Acetonitrile.