On Improving the Cycling Stability of P2-Type Na0.67Ni0.33Mn0.67O2 Cathode Material By Ti-Substitution for Na-Ion Batteries

Wednesday, 16 October 2019
Grand Ballroom (The Hilton Atlanta)
D. Pahari and S. Puravankara (Indian Institute of Technology Kharagpur)
The extensive studies over the last decade have established Na-ion batteries (NIBs) as one of the cheaper alternatives to Li-ion batteries (LIBs) [1-2]. P2-type Na0.67Ni0.33Mn0.67O2 has stood out among layered oxide based electrode materials providing the best over-all electrochemical performance. The electrodes can exert up to 92.5% of its theoretical capacity (160 mAhg-1) at a voltage higher than 3 V accounted for the Ni2+/Ni4+ redox. However, at higher voltages, electrodes suffer irreversibility due to P2-O2 structural transition [3]. Recent studies in suppressing this transition by partial substitution with various metals on either Ni or Mn lattice site have suggested enhancing cycling stability [4-7]. In this study, a novel cathode material with Ti-substitution on Ni site, P2-type Na0.67Ni0.25Ti0.08Mn0.67O2 has been synthesized via solid-state synthesis method and characterized electrochemically. Na0.67Ni0.25Ti0.08Mn0.67O2 electrodes have been observed to be highly reversible at higher voltage ranges. The electrodes have an initial discharge capacity of 125 mAhg-1 and can retain around 84% of this capacity (105 mAhg-1) even after 50 cycles at 0.1C when cycled at an upper cut-off voltage of 4.3 V (Figure 1). Na0.67Ni0.25Ti0.08Mn0.67O2 electrodes are believed to suppress the irreversible P2-O2 transformation by diverting the charging reaction through a more reversible P2-OP4 transition.

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