Achieving both high energy and power density, two traditionally opposed battery metrics, requires moving away from the 200+ years-old 2D layered battery configuration to a three-dimensional all solid-state battery (3D SSB) configuration. The enhanced power and energy benefits bestowed by a 3D SSB design have been demonstrated in the Li-ion 3D SSB literature.¹ However, due to limitations in thermal and electronic conductivity of Li-Ion active materials, 3D Li-ion SSBs are limited to microscale dimensions. A potential means around this limitation is to switch to conductive metal electrodes such as Zn and Ag, for which 3D architectures have been demonstrated.² In such a case, the remaining roadblock to a macroscale 3D SSB is the submicron-thick solid-state electrolyte, which requires a non-line-of-sight deposition method for incorporation into the complex 3D base electrode. Initiated chemical vapor deposition (iCVD) is a non–line-of-sight method that is ideal for generating conformal polymer coatings on complex 3D architectures. We focus on polymers amenable to iCVD protocols that can be modified post-deposition to introduce anion conduction pathways that can facilitate Ag and Zn redox. Submicron-thick coatings of poly-dimethylaminomethylstyrene (pDMAMS) that are pinhole-free and electronically insulating on both 2D planar and complex 3D electrode architectures are prepared via iCVD. The pDMAMS coatings are rendered anion-conducting through a vapor-phase methylation process and subsequent ion exchange to yield desirable anion species (e.g., OH^–, Br^–, or HCO₃^–). X-ray photoelectron spectroscopy, ATR-IR spectroscopy, and solid-state magic-angle spinning NMR spectroscopy confirm the structure of the pDMAMS film before and after quaternization, while atomic force microscopy and cyclic voltammetry with redox probes confirm conformality and absence of pinholes in the submicron film. With the use of cyclic voltammetry and AC electrochemical impedance spectroscopy, the electronic and ionic conductivities of the polymer films are measured before and after quaternization. Molecular dynamics simulations of pDMAMS as a function of anion and H2O content in the film are used to generate computational results (e.g., glass-transition temperature Tg, anion conductivity) for comparison to experimental results.

1. Long, J.W.; Dunn, B.; Rolison, D.R.; White, H.S. Chem. Rev. 2004, 104, 10, 4463–4492.

2. Parker, J.F.; Chervin, C.N.; Nelson, E.S.; Rolison, D.R.; Long, J.W. Energy Environ Sci. 2014, 7, 1117-1124.