Anode-Free Lithium Metal Battery Enabled By Planar Lithium Growth in Ionic Liquid Electrolyte

Sunday, 9 October 2022: 10:20
Galleria 4 (The Hilton Atlanta)
S. Hou and C. Wang (University of Maryland)
In this study, we will present an ionic liquid electrolyte that supports the highly reversible Li metal anode with the cycling coulombic efficiency of ~99.9% at the areal capacity of 5 mAh cm-2. A unique planar growth behavior was observed with operando atomic force microscopy, resulting in an oriented, stack-like lithium deposit. This behavior results from the electrochemically stable solid-electrolyte interphase (SEI) and the stiffened electric double layer near the polarized electrode. The smooth and flat lithium deposit favors lean electrolyte, and the anode-free LiNi0.8Mn0.1Co0.1O2 || Cu cell has an energy density approaching 450 Wh kg-1. The SEI composition and the controlling factor of the lithium growth in this electrolyte will be discussed in detail.